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Some of the isotopes occur in nature. For example, in nature there is Uranium 238, and Uranium 235, but only Uranium 235 can directly be used for a power plant (or for an atomic bomb). Uranium is collected, and the isotopes must then be separated. This requires some rather advanced technology.

Sometimes isotopes are created at a reactor. Some material, perhaps Uranium 238, is kept close to the reactor, and while it absorbs neutrons, it changes to another element and isotope, one that can be used in a nuclear reactor.

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