by winning the lotto at lilycove city but you'll have to get all numbers matched
2nd master ball? theres only 1 type of master ball!
To get an additional master ball, you must either trade it from another Pokemon game, or use cheats to get one.
to get a 2nd master ball trade with 50 diffrent people and go see a man in black in the castela pokemon center
The prize for the 2nd puzzle in the Trick House on Pokemon Emerald is a Timer Ball. To access the 2nd puzzle of the Trick House you need the Dynamo Badge from Wattson in Mauville City.
The game only provides you with one, but there is a glitch that lets you use it multiple times. On your first Pokemon's move, you select Items-Balls-Master Ball On your second Pokemon's move, you go to the Master Ball and move it using Y. You can then exit out and do whatever you want to do. On your first Pokemon's turn, you'll throw the Master Ball, but it's still in your backpack. Very handy.
let juniper give you one or trade 50 times and talk to the man at the 2nd floor of the Pokemon center of castelia city
go to slaport :)
You can get 4 master balls in pokemon crystal. 1st 2nd & 3rd: AFTER you defeat the gym leaders of Johto find prof.oak & he will give you 3 master balls! 4th: AFTER you beat the elete 4 and the champion you go to prof.elm and he will give you 1 master ball!
At The Direct Corner At Pokemon Center 2nd Floor
you cant find a master ball but Cyrus gives you one to catch giritina after u beat him for the 2nd time
The smallest room in Meteor Falls, on the 2nd Floor.
Brawly is the 2nd gym leader at dewford town.