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The two factor Van de Waals gave as correction for real molecules instead of the ideal gas, are the size of the molecule, and the amount of attraction between the molecules. The larger the size of the molecule for the greater the deviation from an ideal gas, clearly bromine wins here since it has the biggest size of its atom. The amount of attraction between molecules is directly proportional to the boiling point of the liquid made from those molecules, and again bromine wins here since its has the highest boiling point. So bromine has the greatest deviation from ideal gas behaviour.

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Q: Which gas of the following will have the greatest deviation from ideal behavior H2 F2 Br2 and Cl2?
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