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john
Barnabas accompanied Paul.
It depends upon the journeys. the short answer is that over all the journeys Paul was accompanied by Peter, Barnabas, Timothy, Silas, John Mark (author of the Gospel of Mark) and Luke amongst others.
Mark who wrote the gospel of Mark after the death of christ was from the early christian church. He accompanied Paul and Barnabas on their first missionary journey
1st Missionary Journey - Barnabas. 2nd Missionary Journey - Silas. 3rd Missionary Journey - mostly alone, but assisted at various times by Luke, Timothy or Titus.
Because Luke accompanied John on their journey to Rome
Missionary
I think its in Antioch
Timotheus
timothy
Paul visited Athens and Corinth on the Second Missionary Journey. He also visited Corinth on the Third Missionary Journey.
1 and 2 Thessalonians were written during Paul's Second Missionary Journey.