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The first person Odysseus met was Eumaeus his swineherd.
Elpenor
Odysseus first encounters, on Phaeacia, the princess Nausicaa, daughter of the Phaecian king Alcinous, there with her maids to wash clothes in the river.
Odysseus encounters different kings and queens. please be more specific
He asks Odysseus to make him a burial mound.
Odysseus encounters the cyclops Polyphemus, son of Poseidon on his journey back from Troy.
They were canniables so they eat all of one ship of Oddysseus' men.
Cyclops Polymephus, the island of Hyperion, and the island of Calypso
Jim first encounters her two boys.
Odysseus goes to the underworld and sacrifices a black lamb. The blood of the sacrifice draws spirits to Odysseus, including Tiresias. Odysseus guards the blood with his sword from the other spirits before Tiresias arrives.
Antinous is the first suitor Odysseus kills.
During Odysseus's travels he encounters several monsters and threats. Two of them are female, Circe and Calypso. They both held him on his island for an elongated amount of time.