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Weak move sets and lousy defence make ganondorf the weakest Smash Bros character. Followed by luigi who hurts himself. The only reason why luigi is not the weakest is because when ganondorf's shield breaks it is an instant KO.
You don't, because the Mii isn't a playable character. The Mii, however, will be a playable character in the next Super Smash Bros. games, Super Smash Bros. for Wii U and Super Smash Bros. for Nintendo 3DS.
What character?
The fastest playable character in Super Smash Bros. Brawlis Sonic the Hedgehog.
No, Jack Skellington is not a playable character in Super Smash Bros. Brawl.
Shadow is not a character in Super Smash Bros Brawl, unfortunately.
Master hand is not a playable character in any of the smash bros games.
peach
Yes, he will be a playable character in Super Smash Bros. for Wii U and Super Smash Bros. for Nintendo 3DS (both of which are Super Smash Bros. 4).
Mario
No, Raichu is not a character in Super Smash Bros Melee and is unplayable
there is no main character