The song to which I believe you are referring is the Rolling Stones song, Gimme Shelter. However the woman singing is not Grace Slick but, according to Wikipedia, is guest vocalist Merry Clayton. She definitely sounds very much like the great Grace Slick.
The cast of Gimme Shelter II - 1999 includes: Robin Kipp as Host
Weather Proof - 2009 Gimme Shelter was released on: USA: 9 October 2010
Nikki - 2000 Gimme Shelter 2-8 is rated/received certificates of: Mexico:B USA:PG
Capitol Critters - 1992 Gimme Shelter 1-9 was released on: USA: 1995
On Cinema - 2012 'I Frankenstein and 'Gimme Shelter' 4-3 was released on: USA: 22 January 2014
Party of Five - 1994 Gimme Shelter 3-9 was released on: USA: 13 November 1996
Butterflies - 1978 Gimme Shelter 3-6 is rated/received certificates of: UK:PG (video rating) (2005)
Nash Bridges - 1996 Gimme Shelter 4-13 is rated/received certificates of: USA:TV-PG (V)
Ah, isn't it wonderful how music can bring joy to our hearts? Some songs with "gimme" in the title are "Gimme Shelter" by The Rolling Stones, "Gimme! Gimme! Gimme! (A Man After Midnight)" by ABBA, and "Gimme More" by Britney Spears. Just like painting a happy little tree, music can add color to our lives and bring a smile to our faces.
gimme shelter by the rolling stones
Party of Five - 1994 Gimme Shelter 3-9 is rated/received certificates of: Argentina:13 USA:TV-PG