The first Federally-issued 100 bills were printed in 1862. Please check your bill again and post a new, separate question with more information that might help to ID it.
There is no such thing as a three dollar bill.
Ulyses S. Grant is on the fifty dollar bill.
Alexander Hamilton
Patel Familys
Tomas Jefferson
William McKinley
Benjamin Franklin is on the US $50 bill.
U. S. Grant
President Ulysses S. Grant
Salmon P Chase
The US $50 bill shows a picture of President Ulysses S. Grant.
George Washington. From 1928 to 1934, the one dollar bill was actually known as a Silver Certificate.