James Madison, 4th President of the Unites States, is on the $5,000 bill. Very few of these bills were printed and production was discontinued in 1945. Even though they remain legal to spend they're now collector items and worth much more than $5,000.
US bills higher than $100 are no longer in circulation. They're technically still legal tender but in 1969 President Nixon ordered that banks should no longer distribute high-denomination bills, as a way to limit their use in organized crime.
James Madison
There is no such thing as a three dollar bill.
Ulyses S. Grant is on the fifty dollar bill.
Alexander Hamilton
Patel Familys
Tomas Jefferson
William McKinley
Benjamin Franklin is on the US $50 bill.
U. S. Grant
5000
President Ulysses S. Grant
Salmon P Chase