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Q: Why NMr spectra is recorded in ppm?
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Why does a triplet occurs in C-13 nmr spectra with CDCl3?

In this case, carbon nuclei can couple with deutrium one and the spin quantum no. (I) of deutrium is 1. So according to the famous formula to find the multiplicity of a signal (2nI+1) in NMR, it comes out to be 3 i.e. triplet.