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This is due to electrification process. As we rub the comb along with hair, the molecues in the comb would lose some electrons to the hair. This happens due to friction. So comb due to lack of negatively charged electrons becomes positively charged. Same time hair gaining electrons becomes negatively charged.

Now as we keep this charged comb close to a bit of paper, then by electrostatic induction opposite charges here negative electrons are pulled towards it. So paper gets negative charge momentarily. Hence force of attraction between unlike charges. So paper bit gets attracted.

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Q: Why a comb drawn through hair attracts a tiny piece of paper?
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