The lone pair - OH bond repulsion in water is greater than the OH bond- OH bond repulsion. In methane all of the bonds are the same so it has perfect tetrahedral symmetry. This is VSEPR theory
The HOH bond angle in water is 104.50, the HSH bond angle in hydrogen sulfide is less at 92.10. The O-H bond length is 95.84 pm and the S-H bond length is longer at 133.6 pm.
Two explanations, the most intuitive is the VSEPR:-
VSEPR theory- this predicts that the lone pair-bonding pair repulsion is greater than bonding pair-bonding pair. This explains why the HOH angle is decreased from the ideal tetrahedral shape. In H2S the reduced electronegativivty of the S atom leads to the lone pair bing further away from the atom and causing an even greater repulsion.
Hybridisation- as you go down group 16 the tendency is for s electrons to take less part in the bonding and the angles get closer to 900 as the p "character" increases.
Maybe because the flourines are the most electronegative atom in Periodic Table so they pull each other closer making F-O-F bond angle smaller then H-O-H bond angle.
H2 molecule is the least polar. Between H2O and H2S, the most polar will be H2O as oxygen is more electronegative than sulphur.
It is not using H2S gas. It is using H2O liquid.
h2so4 being good oxidising agent oxidises the h2s to h2o and free sulphur.so conc h2so4 cant be used in preparation of h2s gas
H2o,co2,so2,h2,co,h2s,hcl,hf
Yes. NH3, H2O, H2S, H2SO4; anything without carbon is an inorganic compound.
The bond angle for H2S is 92.1­°.
The larger the central atom is the less the hydrogens have to spread out (because the electron repulsions are smaller) and the smaller the resulting angle.
H2 molecule is the least polar. Between H2O and H2S, the most polar will be H2O as oxygen is more electronegative than sulphur.
intermolecular hydrogen bonding that is prsnt in H2O while absnt in H2S....:)
NH3 is more polar than AsH3, this is the same as comparing H2O and H2S.
Strongest---------------> Weakest HI, HCl, H2S, H2O According to MasteringChemistry.com
It is not using H2S gas. It is using H2O liquid.
liho+h2s=
h2so4
Ch3conh2 + h2s
h2so4
Water. The shape of the H2S atom is not quite identical to the shape of H2O, because the angle the atoms make is a few degrees off.