That can depend on a great many things. Pikachu normally learns thunderbolt at level 29, so if you caught it at a higher level, it may not have learned it (similar to when you decide to delete a move when your pokemon already knows four), or it may not be a high enough level to learn it yet.
pikachu learns thunderbolt at level 26
Pikachu learns Thunderbolt at level 29.Pikachu learns Thunderbolt at Level 29.
Pikachu learns thunderbolt at level 26.
Pikachu learns Thunderbolt at lvl 26 in Pokemon Yellow.
It should learn it around level 45 or 50 if you don't want to wait then use the TM23.
Pikachu Learns ThunderBolt at level 26 (95 Pwr)(15 PP)
Yes, it learns Thunderbolt at level 26.
It learns thunderbolt at level 26.
Lv 26
yes pikachu can also if you need any other help on moves in pokeman goto serebii.net
It doesn't learn moves you need to teach pikachu the best moves (thunderbolt,thunder,slam,quick attack) Then evolve pikachu into raichu.
A pikachu can learn thundershock, growl,thunderwave, tail whip, quick attack, double team, slam, thunderbolt, agility, thunder, and light screen by itself.