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During the late Middle Ages and Renaissance, miners digging for copper in the German region of Sachsen encountered ore that smelted into both that metal and a much harder silvery metal. Its hardness gave them so much difficulty that the miners thought it had been placed there by the devil.

The new metal was soon called Kupfernickel, or "Old Nick's copper", using a slang name for the devil. When the Swedish mineralogist and chemist Baron Axel Fredrik Cronstedt finally isolated the substance in 1751 he simply eliminated "Kupfer" from Kupfernickel in the same way he had eliminated copper from the ore, giving the metal its modern name.

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