ionic substances do melt, but they just have really high melting points. this is because they're held together by the attraction of opposite charges (two ions (charged atoms)), whereas covalent bonds are held together by the sharing of electrons between two neutral atoms. so, naturally, covalent bonds are more easily broken, so they have a lower melting point.
If the question is "Why do etc." then: Ions in an ionic crystal are held together by ionic bonds aka direct electrostatic interaction, a fairly strong force. Metal atoms in a metal are held together by the metallic bond, which is weaker than an ionic bond or covalent bond but still pretty strong. Molecules in a molecular crystal are held together by covalent bonds internally, but the forces between molecules are at best relatively weak interactions (London or van der Waals type forces).
covalent compounds have weaker bonds than those of ionic.
To melt a network solid, a significant amount of energy is required to break the strong bonds holding the atoms or ions together. These bonds are typically covalent or ionic in nature and must be overcome for the solid to transition into a liquid state.
Ionic bonds typically melt at lower temperatures compared to covalent bonds. Ionic bonds involve the attraction between positively and negatively charged ions, which are held together by electrostatic forces. In contrast, covalent bonds involve the sharing of electrons between atoms, which requires more energy to break.
Almost all molten covalent compounds are much worseconductors than almost any molten ionic compounds. However, note that some ionic compounds contain covalently bonded polyatomic ions, and many of these can conduct electricity as well as most other ions in a melt.
Helium Neon Argon Chlorine Naphthalene (C10H8) Iodine Bromine Solid paraffin (C28H58) KCl Solid wax (C20H42) RbBr CsI Brass Quartz Diamond ------- Argon Solid Was (C20H42) Iodine KCI Brass
because covalent compounds form distinct molecules, in which the atoms are bound tightly to one another. Unlike in ionic compounds, these molecules don't interact with each other much (except through relatively weak forces called "intermolecular forces"), making them very easy to pull apart from each other. Since they're easy to separate, covalent compounds have low melting and boiling points.
Melting a crystal implies that the lattice structure has to be broken down. Ionic compounds have strong lattices held together by electrostatic ionic bonds and generallly have high melting points.
the covalent compound will melt first. Generally this is true as most covalent compounds are made up of small molecules and this leads to low melting points. However giant covalent compounds are high melting. SiO2 melts at over 1600 C whereas common salt (NaCl) melts at only 801 C.
Yes, the strength of the bond between molecules in a substance does influence the temperature at which it melts. Substances with stronger intermolecular forces will have higher melting points as more energy is needed to overcome these forces and change the substance from a solid to a liquid.
CaCl2 is an Ionic molecule. With Electronegativities of 1.00 and 3.16, a difference of 2.16, this falls into the category of Ionic Bond. The scale I have always used is 0-0.39 Non Polar Covalent, 0.4-1.79 Polar Covalent and 1.8 and Up Ionic. If you have a sample to test, you could heat it on a hot plate, Ionic compounds don't melt too well, you could also dissolve it in water as ionic compound typically dissolve well in water.
breaking covalent bonds