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First an explanation in terms of ionization energy and electron affinity:

Metals have low ionization energies and readily form ions. Non-metals have high electron affinities- so put them together and electron transfer is favourable.

Two bonded non metals are generally covalent- their ionization energies are high.

Now an explanation in terms of electronegativity (electronegativity is related to ionization energy and elctron affinity)

metals have low electronegativity- non metals are comparativelly high. So electron transfer is likely.

Just a cautionary word about compounds of non metals never being ionic-- what about PBr5- a binary compound of two non metals- in the solid state this has the structure PBr4+ Br-...bit of a cheat really as there is a polyatomic ion in there but it is ionic!

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Lewis Streich

Lvl 13
3y ago

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