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When you bite aluminum foil, the combination of silver amalgam fillings, saliva loaded with electrolytes, and the aluminum creates a small electrical charge, not unlike the charge you would feel if you were to put your tongue on both terminals of a 9-volt battery. The difference is that this charge is much closer to the nerve of the tooth, which is stimulated and can only signal pain.

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Q: Why do your teeth hurt when you bite foil?
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Why do teeth hurt when you bite foil?

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