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The heat from the burning wood below causes the air to rise; the hot air has a density lower than the cold air and consequently a trend to rise.

The fine ash has also a very low density; consequently can be carried by warm air rising in the atmosphere.

So any of the ash that is released from the wood above the heat of the fire will rise until the air cools.

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Q: Why does ash from burning wood go up into the air?
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