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Because Chloropropane is an alkane but tert-butyl alcohol is an alcohol. The O-H bond is much more difficult to break than the C-H bonds in the hydrocarbons that make up chloropropane. O-H bonds need more energy to break them; therefore the tert-butyl alcohol has a higher boiling point than chloropropane.

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15y ago
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14y ago

It isn't; their boiling points are (ethanol) 78.4oC and (Propanol) 97.1oC. The boiling point of propanol is greater because it is the third member in the series (with 3 carbon atoms) and ethanol is the second (with 2 carbon atoms). While they have similar bonding characteristics, propanol is simply heavier.

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13y ago

1-butanol has higher boiling point becasue of hydrogen bonding between the terminal hydroxyl groups. In tert-butanol the hydrogen bonding is hindered by the methyl groups sticking out of the carbon atom carrying the hydroxyl group.

Wikipedia confirms it.

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12y ago

This is because the polar -OH group can 'hydrogen bond' easier to other similar molecules when it is excentrcally placed, almost outsided.

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Q: Why does 1-butanol have a higher boiling point that tert-butanol?
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