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Let's look at what humidity is. Humidity is the level of moisture in the atmosphere. What are clouds made of? Electrically charged water molecules. Because of being electrically charged, these molecules bond to each other, forming a cloud. This cloud receives more and more water vapor, until it cannot hold any more, and it releases the water vapor in the form of precipitation. Keep in mind though, this doesn't always happen (the rain), when there is moderate to high humidity , but there does have to be high levels of moisture in order for rain to occur.

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Q: Why does it rain when the humidity is high?
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