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Before a burette is used, it needs to be cleaned. During the cleaning process, usually, water is introduced into the burette. Be the water clean or not, if the burette is then used without rinsing it with the solution that it is going to be filled with, the result of that analytical exercise will not be precise and accurate. The reason is that water residue in the burette would dillute the solution when it's filled in the burette which would make it impossible to determine the exact concentration of the solution moved by the burette. By rinsing and re-rinsing the burette several times with the solution it is going to be filled with, residue water from the cleaning process would be successfully removed from the burette as are other leftover substances from the cleaning process. This practice is quite important as basic analytical technique.

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17y ago
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9y ago

This is to avoid contamination. If the burette were rinsed with water and then filled with the solution, the solution in the burette would be of different concentration than it was filled with.

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Sarah Maria

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1y ago
thank you

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13y ago

Sodium hydroxide acts as the titrant in some reactions, particular acid-base reactions where phenolpthalein is used an an inicator of the equivalence point, this is so because phenolpthalein is colourless in acid an pink in base. As the NaOH is titrated against the acid it will easier to see the colour change go from colourless to faint pink rather than from pink to colourless. So to avoid titration errors the NaOh is placed in the burette

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14y ago

so that any residual water or any other solvent used to clean the burette doesn't decrease the original concentration of the solution you want to fill in the burette. hence it is rinsed with the same solution with which it is to be filled

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11y ago

It doesn't necessarily have be rinsed with NaOH, but rather whatever you are going to be putting in there during titration. Is you were going to fill the burette with HCl for example, then you would rinse it with that. It's done in order to stop contamination in your titration, which could lead to impurities and an incorrect titer value.

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14y ago

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Because then you would carry your previous measured solution to your next measuring.

This results in contamination.

In layman's term, contamination = bad

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9y ago

This is to avoid contamination from residue still inside the burette. If another solution is used, that rinsing solution could dilute or contaminate the liquid being tested.

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7y ago

The purpose of this operation is to avoid any contamination of samples.

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6y ago

The burette must be prerinsed with a titrant solution to avoid any contamination.

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6y ago

The purpose is to delete any other impurities.

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Q: Why is it necessary to rinse the burette with sodium hydroxide before you completely fill it up?
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Why ist necessary to rinse the clean burette before filling it with the unstandardised sodium hydroxide solution?

It is a rule of safety in chemistry: to remove any micro-drops of water from the pipette.


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Why is it important to clean a burette?

It is important to remove the filter funnel before adjusting the level of the burette so as to prevent the residual drops of the reagent from dripping into the burette. Which can lead to inaccurate volume readings.


How to clean a burette before fill it with hydrochloric acid?

Rinse with distilled water and blow dry with compressed air.


How would your results have differed if the tip of the burette was not filled with sodium hydroxide before the initial volume reading was recorded?

You would be lead to assume that there was more NaOH in the pipet than there actually was. Since when for example the pipet reads 10ml this is talking when the space in the burette is also filled up. When it is that the reaction takes place between the NaOH and acetic acid you would think that you used more NaOH than you really did, which will ultimately make you think more acetic acid was in the vinegar than was in fact.


What is the proper way to read a burette?

Any fluid!!! It is like a pipette, however, it is usually more accurate because you can use a burette loader which allows fine tuning of the liquid but not as fine as a gilson pipette. Basically, it is just a piece of apparatus used measuring liquids.


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What happens if the tip of the burette is not filled before the titration begins?

The measure of volume used in the titration will be inaccurate, because there will appear to be more titrate used than has actually been dispensed.


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Plus 1 charge