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Across the period, the total number of shells remain the same. But, atomic number, i.e., no. of protons and electrons goes on increasing. Protons (positively charged) present in the nucleus exert a nuclear charge towards the electrons (negatively charged) present around the nucleus, and pull the shells toward the nucleus. Hence, when no. of protons increases, nuclear charge also increases and hence it pulls the shells with greater force, and shells get closer to the nucleus. Hence, across the period, atomic size, or the radii go on decreasing.

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Q: Why does the element with lowest atomic number have the greatest atomic radii in each period?
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