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White colour comes from the mixing of many wavelengths. If you take one grain of a crystal, such as sugar or salt, where the atoms are arranged more or less orderly, the the light isn't as diffused as it would be if you have many but smaller grains. Many grains end up mixing the light and refracting it from many different angles and so producing a white colour.

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Q: Why does the sugar-grain though it is transparent appears white when it is crushed?
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