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Alkynes always form a triple bond. This being so, essentially, all you have are the two carbon molecules and the triple bond! No matter what way your turn it, or how you look at it, even if in a mirror (ie. optical isomerism) you will always have the same looking molecule while to have a geometrical isomer cis or trans form should be there.

gen equation for a compound to be a geometrica isomer:

1.YXC = CXY

2.YXC = CXZ

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12y ago
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11y ago

An alkene cannot rotate with respect to its double bond. Hence, they may show geometrical isomerism, they should always not.

As an example, 1-butene does not show geometrical isomerism whereas 1-chloro-1-butene does show.

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14y ago

Geometrical isomerism is possible for those compounds in which free rotation about bond is not possible in alkenes a double bond restrict the free rotation so arrangement of substituents on double bounded carbon may occur in two ways, same groups at same side of the plane of double bond (Cis) or at opposite side (Trans).

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13y ago

It is because geometric or stereo-isomerism occurs in those compounds which contain double bonds in their molecules.

But none of the alkanes have double bonds.

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10y ago

it is because in case alkynes each carbon has just one valancy left to form bond with other carbon or substituent. so c-c tripple bond forces that portion to be linear(180)

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6y ago

Alkenes have isomers.

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Q: Why don't alkanes have geometric isomers?
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