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For one, there is no reason to chill the liqour. They serve straight liquor on ice or with a mixer that is chilled (generally). Also, when they serve liquor on the rocks, as the ice melts, it soften the liquor up a bit and makes it so that it is not so strong.Second, it would make things way too complicated to have to go to the fridge to get a shot of liquor every time someone wanted a drink, not to mention storage space.

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Q: Why don't bars chill their liquors?
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