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temperature of the hot water combined with that of its container is higher than the ambient temperature and when the surrounding air strikes the container, the temperature of the air increase and this increases the vapour state of the air. note, for water to form around the outside of the hot water glass, the temp of the water must be lower than the temp of the surrounding air (condensation).

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Q: Why don't droplets of water form outside a glass of hot water?
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