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You're presuming they don't, which is at least partially an untruth foisted upon you by the manufacturers of "natural" vitamins.

Vitamins in food tend to be absorbed better than vitamins taken as supplements, but there's no biochemical difference between, say, riboflavin manufactured in a laboratory and riboflavin extracted from so-called "natural" sources.

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Q: Why don't man made vitamins work as well as natural vitamins?
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