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Because the peculiar taste of vomit is created after food has sat in your stomach for a while and has had time for the stomach to excreted hydrochloric acid and other things that start breaking the food down. Once it has sat there for several hours, a burp will really taste like vomit. On the other hand, the majority of burping happens just after you eat, as you are expelling air that you swallowed while eating. In this case, these "fresh" burps will taste mostly like what you were eating. The more time something sits in your stomach, (protein will increase gastric emptying time, as do fats, so eating a meaty, fatty meal will cause these contents to sit in the stomach for hours) the more it breaks down and the more it will smell like vomit.

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Q: Why don't more burps taste like vomit?
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