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Calcium is not found as the metal in nature. It prefers to be a compound. Nature abhors energy and always tries to minimize it. That is why iron and steel rust. Nature prefers iron to be lower energy- rust. In the same way, calcium is far lower energy and far more stable as calcium hydroxide than calcium metal. So calcium reacts with water because it is so energetically favorable.

Ca + 2H2O -------> Ca(OH)2 + H2

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