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Because heat is electromagnetic radiation in the infrared region, therefore, it is emitted and absorbed by charged particles. Since there are mainly two kinds of charged particles; protons and electrons, the electrons are the ones involved in the outer part of an atom, and they either emit or absorb the electromagnetic radiation. This is a transfer of energy, which is synonymous with the transfer of electrons.

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Q: Why is a poor conductor of heat a good insulator of heat?
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helium is an insulator (poor conductor) of heat


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