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What makes each element unique is the number of protons in the nucleus. Sodium has 11 protons and Magnesium has 12 protons. The Periodic Table is arranged with the number of protons of each element increasing to the right and down the table. For an element to fit between sodium and magnesium it would have to have fewer than 12 protons but more than 11, which is simply not possible.

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Q: Why is it extremely unlikely that a new element will be discovered that fits between sodium and magnesium on the periodic table?
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