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Plutonium is not the most expensive element; the price depends on the isotopic composition and chemical purity. Being radioactive and toxic is very difficult to work with plutonium, also it is a material strongly urged for nuclear fuels and nuclear weapons.
The price for nuclear weapons grade plutonium (min. 93 % Pu-239) may be 4 000 US $/g, after the published data.

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10y ago

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