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There's two ways to answer this question.

First electron configurations with half-filled sublevels are more stable then electron configurations that don't have half-filled sublevels. Since Selenium is one elctron away from achieving a more stable half-filled sublevel configuration it more readily gives up it's outermost electron, so less energy is requires to remove the outermost electron. Arsenic already has the stable configuration of half-filled sublevel so it wouldn't give up it's electron as readily, so more energy is required to remove it.

Another way to look at it is that Selenium's outermost electron is in a p orbital that already has an electron so there is electron electron repulsion present in that orbital so it's attraction to the nucleus is less which is why less energy is required to remove it so the ionization energy is less. Arsenic has it's outermost electron unpaired in the p orbital so there is no electron electron repulsion present in that orbital so more energy is required to remove it then for Selenium's outer most electron.

Hope this helps!

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11y ago
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15y ago

Arsenic is closer to having a full outer electron shell ( AKA noble gas configuration) , thus it does not want to give up any of its electrons. Germanium is not as close.

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Q: Why is the first ionization energy of arsenic is greater than the first ionization energy of germanium because?
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