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If I remember correctly the needle is connected to a spring and it moves according to the magnetic force produced by a coil connected to the emf. Due to use or mechanical handling, the needle at rest may not mark zero and may be rotated by a significant angle with no emf. You make the null reading to establish the zero of your measurement, so that you can compensate from deviation at rest.

You have a similar situation with a weight scale at home. Upon use, the zero at rest state may shift from its proper place, so before weighting yourself you need to adjust the needle position to read zero with no weight on it.

Hope this helps.

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Q: Why is the null reading necessary for the measurement of an emf?
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