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The electron configuration of a neutral chromium atom is [Ar]3d54s1. The electron configuration for manganese is [Ar]3d54s2. The first electron removed from a chromium atom is the single 4s electron, leaving the electron configuration [Ar]3d5. The first electron removed from a magnesium atom is one of the 4s2 electrons, leaving the electron configuration [Ar]3d54s1. Removal of a second electron from a chromium atom involves the removal of one of the 3d electrons, leaving a configuration of [Ar]3d4, which is not a very stable configuration, and requires more energy to achieve. Removal of a second electron from a magnesium atom involves the removal of the second 4s electron, leaving a configuration of [Ar]3d5, which is more stable and requires less energy to achieve.

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13y ago

The answer is probably not what you would expect. Iron and chromium are both found to readily turn into Cr+3 and Fe+3 ions. Manganese does not naturally form a Mn+3 ion. Why does this matter? When iron, chromium, and manganese go through their third ionization they form their respective +3 ions. Since manganese does not readily form a +3 ion, it takes a greater energy to strip the electron away from it compared to iron and chromium.

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Q: Why is the 2nd ionisation energy of Cr higher and not lower than of Mn?
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