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There are LED's that run on AC. Remember that an LED is still a diode, and it conducts in one direction only. You can place an LED and a resistor across an AC source, and it will work, so long as you consider both the forward bias condition and the reverse breakdown voltage.

Also, there are some dual LED's mounted in one package that are wired back to back. Applying current in one direction makes them glow red, while applying current in the other direction makes them glow green. If you apply AC to them, they glow both red and green, which is yellow. (Colors, of course, vary, depending on the particular diode.) And, if you want to get fancy, you can pulse-width modulate the current and effectively modulate the color.

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