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The solubility difference between methyl alcohol (CH3OH) and benzene (C6H6) is related to the polar nature of methyl alcohol and the non polar nature of benzene. The OH group on methyl alcohol makes this a polar molecule and thus soluble in water. The lack of such a polar group in benzene makes it non polar, and thus insoluble in water.

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Q: Why methyl aclcohol soluble in water and benzene is not?
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