it has a LONE pair of electrons that is sterically unhindered
Because alkali metal is weak oxidizing agent. complexing agent is related with reduction.
complexing agents are ligands that are capable forming complexes with metal ions by the formation of coordinate bond
caco3
caco3
The common name for NH3 is ammonia. Ammonia is often used as a household cleaning agent in a solution of ammonium hydroxide.
Because alkali metal is weak oxidizing agent. complexing agent is related with reduction.
complexing agents are ligands that are capable forming complexes with metal ions by the formation of coordinate bond
caco3
caco3
To increase solubility product constant by complexation
The common name for NH3 is ammonia. Ammonia is often used as a household cleaning agent in a solution of ammonium hydroxide.
They ease with which they donate their outermost electrons which makes them good reducing agents
A good reducing agent is something that can easily lend a hydrogen atom. Nitrogens Hydrogens are in a subshell that is much closer to the nucleus of the Nitrogen atom. This smaller radius results in a greater attraction between the electrons H+ and N share. Bismuth (Bi) has a much larger radius, so the forces are more diluted, and the H+ is more easily removed from the Bi. Because the Nitrogens H+ in NH3 is harder to remove it is a mild reducing agent. Bismuth has a H+ that can be removed easily so it is a stronger reducing agent.
This is an addition reaction that is also a complexing reaction. The ammonia complexes the copper and acts as a ligand. Tetra-amine Copper Chloride is formed which is a deep inky blue color. [Cu(NH3)4]2+ [Cl-]2 + 4H2O
The purpose is for the agent to "bind to a metal strongly enough to prevent metal hydroxide from precipitating, but weakly enough to give up the metal when EDTA is added." -Quantitative Chemical Analysis, 8th edition, Daniel C. Harris
A chelating agent (also known as a complexing or sequestering agent) is a compound that forms stable complexes with metal ions. Control of metal ion activity in aqueous systems is the main use of chelating properties so precipitation of sparingly soluble salts such as those of of calcium and magnesium with inorganic anions, fatty acids and anionic surfactants can be avoided. Typical applications are scale control and water softening.
NH3