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The purpose is for the agent to "bind to a metal strongly enough to prevent metal hydroxide from precipitating, but weakly enough to give up the metal when EDTA is added."

-Quantitative Chemical Analysis, 8th edition, Daniel C. Harris

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What is the principle of complexometric titration?

Complexometric titration is a type of volumetric titration that involves the formation of a complex between a metal ion and a complexing agent. The endpoint of the titration is determined by a color change or a change in a physical property caused by the complex formation. It is commonly used to determine metal ions in solution.


What are the method of titration?

The methods of titration include acid-base titration, redox titration, and complexometric titration. Acid-base titration involves the reaction between an acid and a base to determine the concentration of one of the reactants. Redox titration involves oxidation-reduction reactions to determine the concentration of a substance. Complexometric titration involves the formation of a complex between a metal ion and a complexing agent to determine the concentration of the metal ion.


What are complexing agent?

complexing agents are ligands that are capable forming complexes with metal ions by the formation of coordinate bond


What are different types of titration?

There are several types of titration techniques, including acid-base titration (determining the concentration of an acid or base), redox titration (determining the concentration of oxidizing or reducing agents), complexometric titration (determining the metal ion concentration using a complexing agent), and precipitation titration (determining the concentration of a dissolved substance by precipitating it).


What is the name of the complexing agent used to determine the total hardness?

caco3


What is the full name of the complexing agent used to determine the total hardness?

caco3


What is the difference between iodometric titration and iodimetric titration?

Iodometric titration involves the titration of iodine with a reducing agent, while iodimetric titration involves the titration of iodide with an oxidizing agent. In iodometric titration, iodine is detected by a starch indicator to determine the end point, while in iodimetric titration, iodide ion concentration is determined by titration with a standard solution of an oxidizing agent.


What is the chemistry behind the redox titration?

Redox titration involves a reaction between an oxidizing agent and a reducing agent. During the titration, electrons are transferred from the reducing agent to the oxidizing agent, resulting in a change in oxidation states. The equivalence point is reached when the moles of the oxidizing agent are stoichiometrically equivalent to the moles of the reducing agent.


Why alkali metal is poor complexing agent?

Alkali metals are poor complexing agents because they have a low charge density due to their large atomic size and low charge, making them less effective at forming stable complexes with other molecules or ions. Their tendency to lose an electron to form a stable cation also limits their ability to participate in complex formation reactions.


Role of phosphoric acid in dichrometry titration?

Phosphoric acid is used as a complexing agent in dichrometry titration to improve the selectivity and sensitivity of the method. It forms a stable complex with the metal ions being titrated, preventing their interference with the chromate ion being used as the titrant. This helps in accurately determining the concentration of the analyte in the presence of other metal ions.


Why thiosulphate titration is called as redox titration?

A thiosulfate titration is mostly carried out to determine the amount of iodine present in the solution. In these reactions, thiosulfate ion acts as the reducing agent. This types titrations are often called as 'iodometric titrations'.


Why should excess complexing agent be avoided in gravimetric analysis?

Excess complexing agent can lead to the formation of undesired complexes, interfering with the accurate determination of the analyte's mass. It can also make it challenging to separate the analyte from the complex for weighing. Quantitative results may be affected, leading to inaccurate analysis.