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I don't know where you got the notion that elements of odd atomic numbers have two isotopes, but we don't have to look far for a counterexample: hydrogen... atomic number 1... has not one, not two, but THREE isotopes that exist for meaningful lengths of time.

If you mean STABLE isotopes, then we have to go a bit further: the first four elements of odd atomic number (hydrogen, lithium, boron, nitrogen) do in fact have two stable isotopes. However, at the fifth we find our counterexample: fluorine (atomic number 9) has only one stable isotope, fluorine-19.

Furthermore, helium (atomic number 2) ALSO has two stable isotopes, so we can't even invert the original question and ask why EVEN atomic number elements DO NOT have two isotopes.

The question is therefore meaningless, as it's asking for an explanation of something that does not, in fact, actually happen.

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