a primary standard should essentially available in pure form , stable towards light and heat and react in a stoichiometric proportion.
HCl is a gas which is dissolved in water to form the solution the concentration expressed is very approximate so its not a primary standard.
NaOH cannot be weighed in open air because it is highly hygroscopic.
FeSO4 under goes aerial oxidation .so all these are not used as primary standards .
but they can be used as secondary standards as the solutions have to be titrated each and every day against a primary standard.
because in the preparation of hydrogen gas ......granulated zinc is used n which is the purest form of zinc. if granulated zinc reacts with dilute sulphuric acid .....there , a displacement reaction takes place but the purest form of zinc don't react with concentrated sulphuric acid ..... . i.e ....there will be no displacement reaction ....so hydrogen gas will not be formed
HCl is not typically used as a primary standard because it is difficult to obtain in a pure solid form. Instead, it is usually standardized against a primary standard such as potassium hydrogen phthalate (KHP) or sodium carbonate.
Hydrochloric acid (HCl) is considered a primary standard because it is a highly pure compound that can be used directly to prepare standard solutions for titrations and other analytical procedures without the need for standardization.
Concentrated HCl is not considered a primary standard material because it tends to be hygroscopic, meaning it absorbs water from the atmosphere, leading to inaccuracies in the weighing process. Additionally, concentrated HCl can be prone to decomposition over time, which affects its stability for accurate standardization. For these reasons, it is more common to use a certified primary standard like potassium hydrogen phthalate or sodium carbonate for acid-base titrations.
To standardize an HCl solution with a primary standard Na2CO3 solution, first, prepare a Na2CO3 solution of known concentration. Then, titrate the Na2CO3 solution with the HCl solution using a suitable indicator until the equivalence point is reached. From the volume of HCl solution used and the known concentration of Na2CO3, you can calculate the exact concentration of the HCl solution.
To standardize 1N HCl (hydrochloric acid), you would typically use a primary standard base, such as sodium hydroxide (NaOH), of known concentration to titrate the HCl solution. By carefully titrating the HCl with the NaOH, you can determine the exact concentration of the HCl solution. This information can then be used to adjust the concentration of the HCl solution as needed to make it accurately 1N.
HCl is not typically used as a primary standard because it is difficult to obtain in a pure solid form. Instead, it is usually standardized against a primary standard such as potassium hydrogen phthalate (KHP) or sodium carbonate.
Hydrochloric acid (HCl) is considered a primary standard because it is a highly pure compound that can be used directly to prepare standard solutions for titrations and other analytical procedures without the need for standardization.
NaOH
Concentrated HCl is not considered a primary standard material because it tends to be hygroscopic, meaning it absorbs water from the atmosphere, leading to inaccuracies in the weighing process. Additionally, concentrated HCl can be prone to decomposition over time, which affects its stability for accurate standardization. For these reasons, it is more common to use a certified primary standard like potassium hydrogen phthalate or sodium carbonate for acid-base titrations.
To standardize an HCl solution with a primary standard Na2CO3 solution, first, prepare a Na2CO3 solution of known concentration. Then, titrate the Na2CO3 solution with the HCl solution using a suitable indicator until the equivalence point is reached. From the volume of HCl solution used and the known concentration of Na2CO3, you can calculate the exact concentration of the HCl solution.
To standardize 1N HCl (hydrochloric acid), you would typically use a primary standard base, such as sodium hydroxide (NaOH), of known concentration to titrate the HCl solution. By carefully titrating the HCl with the NaOH, you can determine the exact concentration of the HCl solution. This information can then be used to adjust the concentration of the HCl solution as needed to make it accurately 1N.
NaOH cannot be used as a primary standard because it is hygroscopic, meaning that it absorbs moisture from the air and its concentration can change over time. This makes it unsuitable for accurate and precise standardization. Borax, on the other hand, can be used as a primary standard because it is a stable, solid substance with a known formula weight that can be accurately weighed.
The common primary standard used to standardize NaOH and HCl solutions is potassium hydrogen phthalate (KHP). KHP is a solid acid that can be accurately weighed and dissolved in water for titration with the NaOH or HCl solution.
Another primary standard that can be used to standardize sodium hydroxide is potassium hydrogen phthalate (KHC8H4O4).
The primary standard commonly used to titrate against potassium hydroxide is potassium hydrogen phthalate (KHP). It is a stable compound with a well-defined molar mass, making it suitable for accurately determining the concentration of a solution of potassium hydroxide.
To standardize 0.5 M HCl, you would typically titrate it using a primary standard solution such as sodium carbonate (Na2CO3). By titrating a known volume of the HCl with the sodium carbonate solution and using the mole ratio between the two, you can calculate the exact concentration of the HCl solution. This process ensures that the concentration of the 0.5 M HCl is accurate for future use in experiments.
The chemical formula (not symbol) of hydrogen chloride is HCl; for a diluted solution you can use "HCl dil." but this isn't a standard formula.