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There's no good reason to add vanillin to infant milk powder, but it's technically possible.

There's at least one good reason not to do it, in addition to the general "why mess around adding unnecessary substances to infant formula": vanillin is a trigger for migraines in some people.

Baby milk powder should be only the necessary nutrients. So there is no need to add vanillin because it has no nutritional value. Though vanillin is not bound to an immediate harmfulness for infants, it may affect the baby's choice of food as they get older. As milk powder tastes more sweet with vanillin, babies prefer to eat. After they grow up, it is more likely for them to like sweet food.

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Q: Why vanillin can not be added in infant milk powder?
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