Elend was voted out because the members of the committee felt he was not taking the option of surrender as a viable choice in dealing with the potential invasion.
Zane was in love with Vin, and he was manipulating her. He was trying to get her to leave Elend, and he understood her well enough to be good with the manipulations.
Ruin was released when Vin released the powers of the well instead of taking them for herself. Preservation tried to convince her to take the powers by almost killing Elend.
'The Well of Ascension' ISBN 0765356139
Neither one of them thought that they deserved the other. Also, Vin was keeping secrets from Elend, including that Elend had a very jealous brother.
The hardback edition of 'The Well of Ascension' by Brandon Sanderson has 763 pages.
Elend
Elend discovered Vin's true identity when she accidentally revealed her metal abilities while trying to save him from an assassination attempt. Vin's use of Allomancy made Elend realize that she was more than she appeared to be.
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She wanted to make him the ideal king.
Elend and Vin got married in the Mistborn series by sharing vows and exchanging rings in a traditional ceremony. Their marriage was both a symbol of their love and commitment to each other, as well as a way to solidify their alliance in their fight against evil forces.