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I can hear the mixing bals in my aerosol cans when I shake them even if they are empty. If you do not then perhaps the balls have become stuck for some reason.

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Q: Why when you shake an aerosol can that is full you hear the ball bering but not when empty?
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What is the gas in aerosol cans?

The aerosol-can uses compressed gas as a propellant.Since the product is liquid at room temperature, it is simply poured in before the can is sealed. The propellant, on the other hand, must be pumped in under high pressure after the can is sealed. When the propellent is kept under high enough pressure, it doesn't have any room to expand into a gas. It stays in liquid form.When the button is pressed the pressurized gas pushes the liquid product, as well as some of the liquid propellant, up the tube to the nozzle. Some cans, such as spray-paint cans, have a ball bearing inside. If you shake the can, the rattling ball bearing helps to mix up the propellant and the product, so the product is pushed out in a fine mist.Up until the 1980s, a lot of liquefied-gas aerosol cans used chlorofluorocarbons (CFCs) as a propellant. After scientists concluded that CFCs were harmful to the ozone layer, 70 nations signed the Montreal Protocol, an agreement to phase out CFC use over the next decade. Today, almost all aerosol cans contain alternative propellants, such as liquefied petroleum gas, which do not pose as serious a threat to the environment.


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