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From Thermo-Pad .com FAQ's

What are the white crystals that form in the liquid pad?

If the Thermo-Pad has been stored in its crystallized state for an extended period of time, a small amount of water can evaporate from the pad and cause the solution to become more concentrated. This higher concentration is indicated by "snowflake like" crystals in the liquid pad. The pad will still operate but at a slightly higher temperature. This water loss can be substantially reduced by storing the pad in its liquid state and may be reversed by extending the boiling times and by leaving the pad in water to cool.

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