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As mentioned in the answer to the related question, "Are food contributions to a charitable organization tax-deductible?": Charitable deductions are claimed on Form 1040, Schedule A. You must have a charity's written acknowledgement in your records for donations over $250, and the recipient must be "qualified" under the law and IRS rules. "You must fill out Form 8283 Section A if your total deduction for all non-cash contributions is more than $500. If you make a contribution of non-cash property worth more than $5,000, generally an appraisal must be done. In that case, you must also fill out Form 8283 Section B. Attach Form 8283 to your return."

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