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Charles Goodyear was born to a family that included his father, Gideon Goodyear, a prominent local businessman, and his mother, Mary Goodyear. He married Clarissa C. Smith in 1834, and together they had five children: Charles, Mary, James, George, and William. Goodyear's family played a supportive role in his life, particularly during his struggles to develop the vulcanization process for rubber.

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