No the blend door not functioning will not cause fog; it may however prevent the windows from being defogged or defrosted.
If the widows only fog up when the defroster is on, then you either have a coolant leak in the heater core or your air conditioner compressor isn't working (the AC is used to dry the air when the heat is on).
Blend door actuator failure.
The most common cause of this failure is a broken blend door. Check heatertreater.net for diagnostic information and an inexpensive fix.
The blend door is jammed
Check the safety switch at the top of the driver's door control module. If on, it locks all windows except driver's.
Start with: Possible control, blend door or blend door actuator, low pressure switch, leak in system.
The blend door actuator on late model Dodge Durango and small pickup can be accessed by removing the glove box. There is a very common problem with blend door failure in these vehicles, and dash removal is required to perform the repair. A cheap and easy DIY fix for this can also be found at heatertreater. They also make a heater core regulator which bypasses the blend door and can remedy the situation with no dash removal.
Can't say for positive sure, but I would expect the Freestar/Monterey blend door actuator motor to be much like the Windstar. Common failure, easy replacement - about $40 See "Related Questions" below for links to the Windstar related blend door discussions
The blend door is vacuum controlled. Any vacuum leak in the engine system can cause the door to not function properly. Check this system first. The door could be physically sticking but a vacuum leak is a more common problem.
I do not have heat in the car and the blend door clicks. How do I access the blend door in a 2005 Ford Explorer?
The most common problem causing a 2000 Blazer to stay on heat is a problem with the blend door. Check the blend door and its control circuit to fix the problem.
The blend door actuator is located behind the glove box, and a sign of failure is an audible "clicking" sound when you adjust your climate controls. The most common issue with heat or A/C in the late model Ford windstar is a broken blend door. A broken blend door actuator is almost as common as a broken blend door itself. Typically, the fix requires disassembling the entire dash and replacing the whole plenum box, which can be a costly repair.This details the best DIY option on how to replace a broken blend door or actuator, accessing the plenum box by removing the glove box rather than the entire dash.
The most common problem with heat and a/c in the Ford Windstar is Blend Door failure. The Blend Door actuator on the Ford Windstar can be found by removing the glovebox. A broken blend door actuator is almost as common as a broken blend door itself. Typically, the fix requires disassembling the entire dash and replacing the whole plenum box, which can be a costly repair. Linked here is a video from www.heatertreater.net demonstrating how to access components of the plenum box for repair without disassembling the entire dash.