Yes
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The power to make treaties and confirm the presidents appointments
The first four presidents made many treaties with Indian nation that had many effects and outcomes on Americans. In 1830 Congress passed the Indian Removal Act that allowed the president to make treaties with Native Americans. Although this law did not allow president Jackson to remove the Indians by force he did. This resulted in many protests over the treatment of Indians. Despite the Indian resistance Jackson had managed to push the Indians and further conflict across the Mississippi.
To buy the Indian's land at a cheep price.
It is up to the country not a state to make treaties. It wouldn't make sense for a state to make a treaty with a foreign government because a treaty applies to an entire country and not a particular state.
Presidents don't have legislative power. Congress has legislative powers. Presidents don't make laws.