Hades oversees the souls in the Underworld.
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Hades gives a safe resting place to departed souls.
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Hades does have the ability to punish the souls of the departed if he sees fit.
Hades is the God of the Underworld. Without him there would be no one to preside over the departed souls.
Hermes as the driver of animal herds also became the god who drove or guided the souls of the dead to Hades. In the myth of the abduction of Persephone, he was sent by Zeus to fetch the goddess back from Hades, and was thereafter appointed as the Guide of Dead Souls.